MYOB EXO and MYOB Advanced are the Enterprise solutions that MYOB offer to larger companies and both of these tools have APIs available to them for your consumption.
Having said that they integrations to these are much more complex and very different from integrating to the MYOB SME product range.
To learn more about these, head to http://developers.myob.com/
Applications for API Keys for these products are managed by the Enterprise teams.
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